Correction: Lanthanide separation using size-selective crystallization of Ln-MOFs

Effects of lanthanide metal size and amino ligand denticity on the solvothermal systems Ln/Sn/Se/en and Ln/Sn/Se/dien (Ln = lanthanide).

Two systems, Ln/Sn/Se/en and Ln/Sn/Se/dien, were investigated under solvothermal conditions, and novel lanthanide selenidostannates [{Ce(en)(4)}(2)(μ-Se(2))]Sn(2)Se(6) (1a), [{Ln(en)(3)}(2)(μ-OH)(2)]Sn(2)Se(6) (Ln = Pr(1b), Nd(1c), Gd(1d); en = ethylenediamine), [{Ln(dien)(2)}(4)(μ(4)-Sn(2)Se(9))(μ-Sn(2)Se(6))](∞) (Ln = Ce(2a), Nd(2b)), and [Hdien][Gd(dien)(2)(μ-SnSe(4))] (2c) (dien = diethylen...

Microwave-assisted large scale synthesis of lanthanide metal-organic frameworks (Ln-MOFs), having a preferred conformation and photoluminescence properties.

Preparation of MOF on a large scale is a great challenge due to difficulties in reproducibility. A microwave synthesis procedure plays a major role in solving this problem. Moreover, achievement of the preferred conformation in the case of the flexible ligand is also an important factor as it affects the stability of the MOF. In this regard, lanthanides are suitable candidates due to their larg...

Investigating metal size effects in the Ln/As/Se/amine (Ln = lanthanide excluding Pm, amine = en, dien, en+trien) systems: solvothermal syntheses and characterizations of lanthanide selenidoarsenates.

Three solvothermal systems Ln/As/Se/en, Ln/As/Se/dien and Ln/As/Se/(en+trien) (Ln = lanthanide excluding Pm, en = ethylenediamine, dien = diethylenetriamine, trien = triethylenetetramine) were investigated in detail across the lanthanide series, and ternary lanthanide selenidoarsenates [Ln(en)(3)(H(2)O)(mu-eta(1),eta(1)-AsSe(4))] (Ln = La(1a), Ce(1b), Nd(1c)), [Ln(en)(4)]AsSe(4) x 0.5 en (Ln = ...

Sensitizing and Protecting Lanthanide Ion Emission Using Optically Active Nanocrystals Lanthanide ions (Ln

Three novel lanthanide metal-organic frameworks (Ln-MOFs) constructed by unsymmetrical aromatic dicarboxylatic tectonics: synthesis, crystal structures and luminescent properties.

Three novel Ln(III)-based coordination polymers, {[Ln2 (2,4-bpda)3 (H2O)x]·yH2O}n (Ln = La (III) (1), x = 2, y = 0, Ce (III) (2), Pr (III) (3), x = 4, y = 1) (2,4-H2bpda = benzophenone-2,4-dicarboxylic acid) have been prepared via a solvothermal method and characterized by elemental analysis, IR, and single-crystal X-ray diffraction techniques. Complex 1 exhibits a 3D complicated framework with...